Good point, I had forgotten about diffration. Yes that can generate energy in the range where these thin types of absorbers start to work. Although, by the time is has diffracted and propagated back to the wall then to the listener, I can't see it being at a high enough level to do any real damage. Many modern designs seem to have the sharp diffraction edges of old under control so maybe it's less of an issue than it was anyway. In my listening room, I have measured higher levels of sound energy from the reflections off the rear wall than from the actual direct signal from the speakers. Things generally sound great though as your ear/brain is clever at integrating all this - would prefer it wasn't at such a high level there though!